WATER TREATMENT BOILER WATER TREATMENT where the silica content is high, or if feed water is taken from cement washed tanks. Boiler Hydro Test - Free download as PDF File (.pdf), Text File (.txt) or read online for free. The need for extreme purity of steam for use in high pressure turbines has prompted the development of highly satisfactory devices for separating steam and water in a boiler drum. It is found in surface and well water. Boiler feedwater is usually a combination of returned condensate plus pre-treated makeup water from a softener, reverse osmosis, or other purification system. An increase in temperature results in an increase in electrical conductivity. Volatilization and carryover of silica with the steam may cause hard, glassy siliceous deposits to form on turbine blades that reduce turbine efficiency. silicate, various forms of iron oxide, silica adsorbed on the previously mentioned precipitates, and alumina (see Table 39.1). High boiler water silica content can result in silica vaporization with the steam, and, under certain circumstances, siliceous scale. OR SEARCH CITATIONS It is necessary to maintain silica concentration at a minimum in boiler feed water, because the silica in a boiler, operating at higher pressure and temperature, not only tends to form complex scale causing lowering in boiler efficiency, but evaporates with steam and … To give warning on acidity or alkalinity of boiler water sample. The process of water treatment in boilers is not limited to producing high quality DM water. Silica DOC316.53.01132 Heteropoly Blue Method1 Method 8186 0.010 to 1.600 mg/L SiO2 (spectrophotometers) 0.01 to 1.60 mg/L SiO2 (colorimeters) Powder Pillows Scope and application: For boiler and ultrapure water. Typical tests used for boiler feedwater include: Chloride or salinity Conductivity Dissolved Oxygen Hardness Iron and Manganese pH Silica Sulphite Suspended Solids PH Value (Reciprocal or Hydrogen Ion) Test 7.5 – 14.0 for Boiler Water 6.5 – 10.0 for Condensate Water Purpose: 1. Test preparation Chem. If an economical blowdown rate is to be maintained, suitable boiler water tests must be run frequently to check concentrations in the boiler water. When sodium zeolite softened makeup is used, the need for boiler blowdown is usually determined by measurement of the boiler water conductivity, which provides an indirect measure of the boiler water dissolved solids. 5.1 Control of silica in boiler feedwater and boiler water is necessary to minimize the formation of scale-forming silicates that decrease heat transfer in the boiler. Figure 3-14. You must maintain a Total OH alkalinity ratio of 3:1 in high pressure boilers to prevent plating of silica. Natural waters, generally, contain about 5-8 mg/l of silica (Si0,). Silica content of the boiler water is critical for steam turbines and scaling of boiler heat transfer surfaces. Ind. Silica measurements are required at this point, principally to confirm that the maximum level of silica permissible in the boiler is not exceeded. condensate must also be performed. A boiler water sample has an unneutralised conductivity of 5 000 μS/cm at 25°C. Ed. Scale deposits occur when calcium, magnesium, and silica, commonly found in water supplies, react to form a continuous layer of material on the waterside of the boiler heat exchange tubes. Accordingly, a test for hardness in the. chirag singh - ambala, haryana,india Acmite (Sodium Ferrous Silica - Na 2 Fe 2 O 3 4SiO 2) and crust Fe - Si can be formed from corrosion result. Scale creates a problem because it typically possesses a thermal conductivity less … Manual on Boiler Hydro Test Why does steam carry silica and where does it come from if FEED WATER SILICA is zero? A low-pressure fire-tube boiler can usually tolerate high feed-water hardness with proper treatment while virtually all impurities must be removed from water used in some modern, high-pressure boilers. 5.3 Silica concentration is an important consideration in some industrial installations such as steam generation and cooling water systems. The standard test for the analysis of silica in water is a rapid technique based upon the blue reduced silicomolybdate complex. Consequently, steam contamination has been steadily reduced. Anal. On some new vessels 1 Adapted from Standard Methods for the Examination of Water and Wastewater. Silica (sio2) is an oxide of silicon, and is present in almost all minerals. Silica content of the boiler water is critical for steam turbines and scaling of boiler heat transfer surfaces. The three common kinds of silica are soluble, colloidal and particulate. For most dissolved solids found in boiler water, it is negligible by comparison to mechanical carryover at pressures less than 2000 psig (13.8 MPa). For boiler water, the conductivity increases at the rate of approximately 2% (of the value at 25°C) for every 1°C increase in temperature. If phosphate salts are used to treat the boiler water, calcium will preferentially precipitate as the phosphate before pre-cipitating as the carbonate, and … systems, it is essential to . Silica in boiler feedwater can be a problem in larger steam boiler systems. ¾TIP 0416-03– Water Quality and Monitoring Requirements for Paper Mill Boilers Operating on High Purity Water, 1999 ¾TIP 0416-04– Design Engineer Decision Tree: Paper Mill Boiler Feedwater, 1999 ¾TIP 0416-05– Response to Contamination of High Purity Boiler Feedwater, 2000 ¾TIP 0416-06– Keys to Successful Chemical Cleaning of Taylor’s Boiler & Cooling Water Test Kits INTRODUCTION. Feed-water purity requirements therefore can vary widely. This necessitates the use of a high quality water treatment system. Result help to establish the dosage of boiler compound to fight against corrosion. T. o prevent corrosion and scale in boiler and cooling water . Therefore feedwater treatment must be controlled to eliminate aluminum and silica. Alkalinity Test In natural waters, alkalinity is most commonly the result of bicarbonate and carbonate ions; in treated waters, alkalinity may also be contributed by hydroxide, phosphate, silicate, and other treatment ions. In cooling water systems, silica forms deposits when solubility limits are exceeded. Silica Levels Allowed in Boiler Water. 2. The silica concentration is distributed between the water and vapour phases in a boiler… Alkalinity is a measure of the capacity of water to neutralize strong acids. Reactive silica is the form of silica to be used in RO projection programs. Eng. Boiler water quality is of prime concern to all boiler operators. NOTE -In case of recovery boilers operating at low boiler pressures of I.5 to 2.0 When treating boiler feed water (the combination of boiler makeup and condensate return water), several issues can arise that cause boiler scaling, corrosion, fouling, and system failure.. Below, we break down the most common boiler feed water issues and how to avoid them to help ensure system efficiency and operational safety. Silica is a problem for high pressure boilers, as it exhibits enough volatility that high pressure boilers will have silica carry over to the vapour partition. Silica content of the boiler water is not as … 2.1 Water-Tube Boilers ( Drum Type) - The feed water, boiler water and condensate, for water-tube boilers shall cotiply with the requirements given in Table 1. It is not affected by boiler design. Little aluminum content in feedwater can cause high deposit of silica in boiler water. Water Treatment of Silica. In certain cases, when row water is evaporated and is high in silica, carry-over may admit silica into the distilled water system. The measured silica concentration is compared with reference silica … The stringent water chemistry requirements of Supercritical power plants makes water treatment in boilers a very critical aspect of power plant operation. Under certain conditions, silica forms troublesome silica and silicate scales, particularly on high-pressure steam turbine blades. Silica (SiO 2) Silica scale is not normally found in boiler systems except in minute quantities. Silica – this may be the blowdown controlling factor in softened waters containing high silica. Unlike Carbonate and Sulphate ions, the Chloride ion does not precipitate in the presence of soluble Calcium. Silica Test Kit. All Publications/Website. any clues as to how silica shows up in boiler water when demin supply is less than 2ppb and blow down is treated in an anion resin bed before re-entry to water circuit RE: silica in boiler water pablo02 (Electrical) 14 Aug 03 08:27 An exception is silica for which vaporous carryover can be substantial at lower pressures. PROBLEM TO BE SOLVED: To provide a silica concentration control method in boiler water capable of automatically controlling silica concentration in boiler water upon a boiler being started and upon ordinary operation. Another important source of silica in water is the sand watertreatments filter.When water treated by lime-soda process is filtered through a sand water filter, a good amount of silica dissolves in it (forming calcium and magnesium silicates) due to alkaline nature of waters. Procedures: the pH of the boiler water will decrease until acid conditions result in corrosion of the metal surfaces. Steam contamination (solid particles in the superheated steam) comes from the boiler water largely in the carry‐over of water droplets. Vaporous carryover depends on pressure and on boiler water chemistry. 9 – Boiler Drum Silica build-up is monitored inside the boiler drum. Silica is reaching out of control in super heated steam having value 3.2 to 4.0 PPM, but boiler feed water parameter is TDS-2, pH-8.6, P.Alkalinity-01, M.Alkalinity-02, Total hardness-00 and SILICA IS 00 PPM. SOLUTION: Pressure of boiler water and silica concentration at that time are actually measured. Silica Photometer & Comparator Tablet Reagents - AP181 for use when testing Silica in boiler water Model PBC-DT Professional Boiler Treatment/Boiler Feed and Cooling Water Test… Hach In addition to all of the test offered in Model BT-DT (2350600) this test kit provides testing capability for iron, silica, chlorine, nitrite, and total dissolved solids (TDS). 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